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<Emphasis Type="Italic">cis</Emphasis>-Pt Mediated Assembly of Gold Nanoparticles on DNA
Authors:M Noyong  K Gloddek  J Mayer  Th Weirich  U Simon
Institution:(1) RWTH Aachen, Institute of Inorganic Chemistry, Landoltweg 1, 52074 Aachen, Germany;(2) RWTH Aachen, Central Facility for Electron Microscopy, Ahornstrasse 55, 52074 Aachen, Germany
Abstract:In this work we describe the formation of 1-dimensional (1D) assemblies of cysteamine functionalized gold nanoparticles on DNA using the complex cis-Pt (cis-Pt(NH3)2Cl2) as site specific linker and their immobilization on mica and silicon. The characterization by atomic force microscopy and electron microscopy served as complementary methods. Using atomic force microscopy with additional information of phase images the DNA as well as the Au particles can be visualized independently and be differentiated in the 1-dimensional aggregates. Electron microscopy shows individual particles are arranged as a string of pearls. Dedicated to Günter Schmid in occasion of his 70th birthday.
Keywords:DNA  gold nanoparticles            cis-Pt  self assembly
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