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Submillimeter spectrum and spectroscopic constants of the arsine molecule in the ground vibrational state
Authors:A.V. Burenin,V.P. Kazakov,A.F. Krupnov,A.A. Mel&#x  nikov,S.M. Shapin
Affiliation:Institute of Applied Physics, Academy of Sciences of the USSR, Gorky, USSR
Abstract:The submillimeter spectrum of the arsine molecule, AsH3, of both the allowed R-branch transitions (J + 1 ← J, J = 0, 1, 2, 3) and forbidden transitions of the Q branches, |K| = 4 ← 7, 5 ← 8, 6 ← 9, is investigated in the frequency range from 220 to 900 GHz. Weak absorption lines were observed by using the spectrometer RAD with sensitivity increased by a nontunable cavity cell. On the basis of the results obtained and microwave data available in the literature the rotational spectrum of the arsine molecule in the ground state is analyzed.
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