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A convenient synthesis of Fe(CO)2(η-S2CNMe2)2 and Fe(η-S2CNMe2)2 from the monodentate dithiocarbamato derivative, [(η-C5H5)(CO)3W(η-SCSNMe2)] and Fe2(CO)9 |
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| Authors: | Salil K Jha BHS Thimmappa Pradeep Mathur |
| Institution: | Department of Chemistry, Indian Institute of Technology, Powai, Bombay 400076, India |
| Abstract: | A high yield synthesis of the carbonyl dithiocarbamato derivative Fe(CO)2(η2-S2CNMe2)2 and Fe(η2-S2CNMe2)2 by photolysis with visible light of solutions containing Fe2(CO)9 or Fe3(CO)12 and (η5-C5H5)(CO)3W(η1-SCSNMe2)] is reported. |
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