| 由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O |
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| 引用本文： | 吴小园,张全争,何翔,陈淑妹,杨文斌,卢灿忠.由氨基酸配位的铜修饰十二核钨单元构成的一维链状化合物(H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O[J].无机化学学报,2006,22(8):1511-1516. |
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| 作者姓名： | 吴小园 张全争 何翔 陈淑妹 杨文斌 卢灿忠 |
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| 作者单位： | 中国科学院福建物质结构研究所,结构化学国家重点实验室,福州,350002 |
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| 基金项目： | 国家研究发展基金;中国科学院资助项目;福建省自然科学基金 |
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| 摘 要： | The design and synthesis of organic-inorganichybrid compounds have aroused contemporary inter-est;not only owing to their diverse structures,but alsoto their potential applications in fields such as catal-ysis,medicine,analytical chemistry and photochem-i…
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| 关 键 词： | 有机无机杂化材料 水热合成 晶体结构 钨多酸 氨基酸 |
| 文章编号： | 1001-4861(2006)08-1511-06 |
| 收稿时间： | 2006-03-08 |
| 修稿时间： | 2006-06-02 |
One-dimensional Chain Polyoxotungstate Decorated with Amino Acid Copper Complex: (H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O |
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| WU Xiao-Yuan,ZHANG Quan-Zheng,HE Xiang,CHEN Shu-Mei,YANG Wen-Bin and LU Can-Zhong.One-dimensional Chain Polyoxotungstate Decorated with Amino Acid Copper Complex: (H3O)3{[Na3(H2O)13][(Cu(Gly)2)2(H2W12O42)]}·11H2O[J].Chinese Journal of Inorganic Chemistry,2006,22(8):1511-1516. |
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| Authors: | WU Xiao-Yuan ZHANG Quan-Zheng HE Xiang CHEN Shu-Mei YANG Wen-Bin and LU Can-Zhong |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002,State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 and State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 |
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| Abstract: | A new compound, (H3O)3{Na3(H2O)13](Cu(Gly)2)2(H2W12O42)]}·11H2O(1), has been synthesized and structurally characterized, which represents the first example of a polyoxotungstate-surface being decorated with amino acid ligand. Two cis-{Cu(Gly)2}2+ engraft into the (H2W12O42)10- with Cu-O bond of 0.241 2(7) nm, and Na+ ions linked these (Cu(Gly)2)2(H2W12O42)]6- clusters into a one-dimensional chain. CCDC: 278000. |
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| Keywords: | organic-inorganic hybrid hydrothermal synthesis crystal structure polyoxotungstate amino acid |
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