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紫外光照射下 Fe-碳纳米管/TiO2 复合材料降解罗丹明 B
引用本文:ZHANG Kan,MENG Zeda,OH Wonchun. 紫外光照射下 Fe-碳纳米管/TiO2 复合材料降解罗丹明 B[J]. 催化学报, 2010, 31(7): 751-758. DOI: 10.1016/S1872-2067(09)60084-X
作者姓名:ZHANG Kan  MENG Zeda  OH Wonchun
作者单位:Department of Advanced Materials and Science Engineering,Hanseo University,Chungnam 356- 706,Korea 
摘    要: The composites comprising Fe-carbon nanotubes (CNTs) on TiO2 were prepared by a modified sol-gel method and characterized by nitrogen adsorption, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and energy dispersive X-ray analysis. The photocatalytic decomposition of rhodamine B (Rh.B) under UV irradiation and air aeration catalyzed by the composites was measured. The photocatalytic activity of TiO2 nanoparticles was significantly enhanced by the large CNT network that facilitated electron transfer between adsorbed Rh.B molecules and the catalyst substrate and the simultaneous occurrence of the photo-Fenton reaction in the presence of Fe particles. A marked acceleration of the decomposition rate was observed with aeration by flowing air aeration due to the formation of the circulatory photo-Fenton system. Chemical oxygen demand of piggery waste was measured at regular intervals to evaluate the mineralization of wastewater.

关 键 词:iron  carbon nanotube  titania  rhodamine B  photocatalytic activity  photo-Fenton
收稿时间:2010-07-25

Degradation of Rhodamine B by Fe-Carbon Nanotubes/TiO2 Composites under UV Light in Aerated Solution
ZHANG Kan,MENG Zeda,OH Wonchun. Degradation of Rhodamine B by Fe-Carbon Nanotubes/TiO2 Composites under UV Light in Aerated Solution[J]. Chinese Journal of Catalysis, 2010, 31(7): 751-758. DOI: 10.1016/S1872-2067(09)60084-X
Authors:ZHANG Kan  MENG Zeda  OH Wonchun
Affiliation:Department of Advanced Materials and Science Engineering,Hanseo University,Chungnam 356- 706,Korea
Abstract:The composites comprising Fe-carbon nanotubes(CNTs)on TiO2 were prepared by a modified sol-gel method and characterized by nitrogen adsorption,scanning electron microscopy,transmission electron microscopy,X-ray diffraction,and energy dispersive X-ray analysis.The photocatalytic decomposition of rhodamine B(Rh.B)under UV irradiation and air aeration catalyzed by the composites was measured.The photocatalytic activity of TiO2 nanoparticles was significantly enhanced by the large CNT network that facilitated electron transfer between adsorbed Rh.B molecules and the catalyst substrate and the simultaneous occurrence of the photo-Fenton reaction in the presence of Fe particles.A marked acceleration of the decomposition rate was observed with aeration by flowing air aeration due to the formation of the circulatory photo-Fenton system.Chemical oxygen demand of piggery waste was measured at regular intervals to evaluate the mineralization of wastewater.
Keywords:iron  carbon nanotube  titania  rhodamine B  photocatalytic activity  photo-Fenton
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