| Electrochemical Polymerization of Brilliant Cresyl Blue and Properties of the Polymer |
| |
| 作者姓名： | 杨一飞 穆绍林 |
| |
| 作者单位： | DepartmentofChemistry,SchoolofScience,YangzhouUniversity,Yangzhou,Jiangsu225002,China |
| |
| 基金项目： | theNationalNaturalScienceFoundationofChina (No.2 0 0 74 0 2 7)，theStateKeyLaboratoryofPhysicalChemistryoftheSolidSurfaceatXiamenUniversity |
| |
| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｄｉｓｃｏｖｅｒｙｏｆｔｈｅｃｏｎｄｕｃｔｉｖｉｔｙｏｆｐｏｌｙａｃｅｔｙｌｅｎｅｈａｓｏｐｅｎｅｄａｎｅｗｒｅｓｅａｒｃｈｆｉｅｌｄｆｏｒｔｈｅｓｙｎｔｈｅｓｉｓｏｆｎｅｗｍａｔｅｒｉａｌｓ .Ｃｏｎｄｕｃｔｉｎｇｐｏｌｙｍｅｒｓｃａｎｂｅｓｙｎｔｈｅｓｉｚｅｄｂｙｔｈｅｃｈｅｍｉｃａｌｐｏｌｙｍｅｒｉｚａｔｉｏｎａｎｄｅｌｅｃｔｒｏｃｈｅｍｉｃａｌｐｏｌｙｍｅｒｉｚａ ｔｉｏｎ .1 7Ｔｈｅｅｌｅｃｔｒｏｃｈｅｍｉｃａｌｐｏｌｙｍｅｒｉｚａｔｉｏｎｐｒｏｖｉｄｅｓａｓ…
|
| 关 键 词： | 电化学聚合 亮甲酚蓝 性质 聚合物 结构 红外光谱 |
Electrochemical Polymerization of Brilliant Cresyl Blue and Properties of the Polymer |
| |
| YANG,Yi Fei MU,Shao Lin.Electrochemical Polymerization of Brilliant Cresyl Blue and Properties of the Polymer[J].Chinese Journal of Chemistry,2002,20(6):583-590. |
| |
| Authors: | YANG Yi Fei MU Shao Lin |
| |
| Institution: | YANG,Yi Fei MU,Shao LinDepartment of Chemistry,School of Science,Yangzhou University,Yangzhou,Jiangsu 225002,China |
| |
| Abstract: | The electrochemical polymerization of brilliant cresyl blue (BCB) has been carried out using cyclic voltammetry in the potential region between ?0.20 V and 1.15 V (vs. Ag/AgCl with saturated KCl solution). The electrolytic solution consisted of BCB (0.1 mol/L) and Na2HPO4(0.2 mol/L) with pH 2.1. BCB can not be polymerized at pH < 1. There are an anodic peak and a cathodic peak on the cyclic voltammogram of poly (BCB) at pH ≤ 4.3. Both peak potentials shift towards more negative with increasing pH value, and their peak currents decrease with increasing pH value. Poly (BCB) depicts a good electrochemical reversibility, fast charge transfer ability and stability in aqueous solutions with pH ≤ 4.3. The visible spectrum, FTIR spectrum and Raman spectrum of poly (BCB) are different from those of BCB. |
| |
| Keywords: | electrochemical polymerization poly(brilli~an~t cresyl blue) electrochemical properties visible spectra FTIR spectra Raman spectra |
| 本文献已被 CNKI 维普 等数据库收录！ |
