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Comparative study on the lamellar structure of polyethylene foams
Authors:O. Almanza,M.A. Rodrí  guez-Pé  rez,B. Chernev,P. Zipper
Affiliation:a Departamento de Física, Universidad Nacional de Colombia, Bogotá, Colombia
b Departamento de Física de la Materia Condensada, Facultad de Ciencias, Universidad de Valladolid, 47011 Valladolid, Spain
c Physikalische Chemie, Institut für Chemie, Universität Graz, 8010 Graz, Austria
Abstract:
A comparative study on the lamellar morphology of a collection of polyethylene foam (LDPE) has been performed in order to obtain a better understanding of the morphology of the crystalline phase of these materials. The lamellar structure was measured by small-angle X-ray scattering (SAXS), differential scanning calorimetric (DSC) and Raman spectroscopy. The results have shown that the lamellar structure of the foams is different to that of a LDPE solid sheet. Moreover, the different sensitivity of the three experimental techniques to the lamellar structure has also been analyzed.
Keywords:Small-angle X-ray scattering   Polyolefin foams   Lamellar thickness   Raman   DSC
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