Interaction d'un jet moléculaire avec un gaz tampon : relaxation collisionnelle d'un système à deux niveaux d'énergie |
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Authors: | JC Chardon C Genty |
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Institution: | Laboratoire de Spectroscopie Hertzienne et d'électronique, UFR des Sciences et des Techniques, 16 route de Gray, 25030 Besan?on Cedex, France, FR
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Abstract: | Using a molecular beam, we study the transitions induced by collisions with molecules of a scattering gas. The experimental
method uses a H2CO beam apparatus which allows the observation of rotational transitions . The target gas is NH3. The application of a static electric field E considerably modifies the collision induced transition probabilities; the transitions become forbidden when Eis intense. An experimental method is deduced to select transitions on a molecular beam. We initially prepare the system to be in the level (i) before entering the scattering chamber.
After scattering, the population ratio n
f/n
i is measured as a function of the target gas pressure P
T. We determine the state to state cross-section of H2CO. When the pressure P
T becomes intense, the effect is non linear. It is shown that this effect results of many collisions. We compare theory with
experimental results. This experimental method gives a model for relaxation process studies in two energy level systems.
Re?u le 30 juin 1999 et re?u sous forme finale le 14 décembre 1999 |
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