Synthesis and electrochemical behavior of clothespin-shaped bisflavin compounds |
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| Authors: | Yasushi Imada |
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| Affiliation: | Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan |
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| Abstract: | ![]()
Clothespin-shaped bisflavin compounds 1 bearing doubly linked 3,3′:10,10′-methylene spacers exhibited significant enhancement of specific association with a variety of neutral aromatic compounds in DMF under electroreduction conditions. This specificity could be rationalized by the ‘electric clip motion’ of intermediate bis-anion radical species. |
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| Keywords: | Bisflavins Electrochemistry Molecular clips Molecular recognition Supramolecular chemistry |
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