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Low-temperature absorption contour of the ν3 band of SF6
Authors:P.L. Houston  J.I. Steinfeld
Affiliation:1. Spectroscopy Laboratory Massachusetts Institute of Technology, Cambridge Massachusetts 02139 USA;2. Department of Chemistry Massachusetts Institute of Technology, Cambridge Massachusetts 02139 USA
Abstract:
A band contour analysis is carried out for the ν3 absorption in SF6. Values of ΔB = ? (1.0 ? 1.5) × 10?4cm?1, ζ3 = 0.701, and ν0 = 948.2cm?1 are found. Tentative assignments are given for the SF6 rotational states which are pumped by the P(14) through P(22) lines of the CO2 laser.
Keywords:
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