Isotactic-b-syndiotactic stereoblock poly(methyl methacrylate) by chiral metallocene/Lewis acid hybrid catalysts |
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| Authors: | Bolig Andrew D Chen Eugene Y-X |
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| Affiliation: | Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA. |
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| Abstract: | Stereoblock polymerization with chiral ansa-metallocene/strong Lewis acid hybrid catalysts capable of switching stereospecificity of the methyl methacrylate polymerization produces the highly stereoregular isotactic-b-syndiotactic stereoblock poly(methyl methacrylate). |
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