Stacking reactions of the borole complex Cp*Rh(η5-C4H4BPh) with the dicationic fragments [Cp*M]2+ (M = Rh or Ir) |
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| Authors: | D A Loginov D V Muratov Z A Starikova P V Petrovskii A R Kudinov |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
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| Abstract: | The reaction of the (borole)rhodium iodide complex (η-C4H4BPh)RhI]4 with Cp*Li afforded the sandwich compound Cp*Rh(η-C4H4BPh) (4). The reactions of compound 4 with the solvated complexes Cp*M(MeNO2)3]2+(BF
4
−
)2 gave triple-decker cationic complexes with the central borole ligand Cp*Rh(η-η5:η5-C4H4BPh)MCp*]2+(BF
4
−
)2 (M = Rh (5) or Ir (7)). The structure of complex 4 was established by X-ray diffraction.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1525–1527, September, 2006. |
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| Keywords: | sandwich compounds triple-decker complexes rhodium iridium |
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