Experimental and theoretical studies on the radical-cation-mediated imino-Diels-Alder reaction |
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| Authors: | Pérez-Ruiz Raul Domingo Luis R Jiménez M Consuelo Miranda Miguel A |
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| Affiliation: | Departamento de Química-Instituto de Tecnología Química UPV-CSIC, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022, Valencia, Spain. |
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| Abstract: | The feasibility of an electron transfer imino-Diels-Alder reaction between N-benzylideneaniline and arylalkenes in the presence of a pyrylium salt as a photosensitizer has been demonstrated by a combination of product studies, laser flash photolysis (LFP), and DFT theoretical calculations. A stepwise mechanism involving two intermediates and two transition states is proposed. |
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