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Intra/intermolecular direct allylic alkylation via Pd(II)-catalyzed allylic C-H activation
Authors:Lin Song  Song Chun-Xiao  Cai Gui-Xin  Wang Wen-Hua  Shi Zhang-Jie
Affiliation:Beijing National Laboratory of Molecular Sciences, College of Chemistry and Molecular Engineering and Green Chemistry Center, Peking University, Beijing 100871, China.
Abstract:The first catalytic direct alkylation of allylic C-H bonds via Pd(II)-catalysis is described in the absence of base. Polysubstituted cyclic compounds can also be constructed by the intramolecular direct allylic alkylation.
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