| 具有手性侧链的卟啉液晶化合物的合成和发光性能研究 |
| |
| 引用本文： | 骆开均,谢明贵,蒋青,邹德春.具有手性侧链的卟啉液晶化合物的合成和发光性能研究[J].化学学报,2004,62(24):2425-2430. |
| |
| 作者姓名： | 骆开均 谢明贵 蒋青 邹德春 |
| |
| 作者单位： | 四川大学化学学院,成都,610016;四川师范大学分析测试中心,成都,610066;四川大学化学学院,成都,610016;北京大学化学与分子工程学院,北京,100871 |
| |
| 基金项目： | 国家自然科学基金 (No.2 0 1 0 2 0 0 4 )资助项目 |
| |
| 摘 要： | 通过在卟啉环上引入手性侧链的方法合成了两类(4个)卟啉液晶化合物,并用元素分析,UV-vis, FT-IR, 1H NMR, MS, DSC,圆二色谱(CD)和偏光显微镜对化合物的结构进行了表征.研究结果表明,这些化合物具有液晶性质,固体荧光和电致发光性质,其中两个卟啉配体有较强的CD吸收性能.
|
| 关 键 词： | 卟啉液晶 合成 圆二色谱(CD) 光致发光(PL) 电致发光(EL) |
Synthesis of Liquid Crystal Porphyrin Compounds with Chiral Side Chains and Their Luminescent Characterization |
| |
| LUO Kai-Jun,XIE Ming-Gui,JIANG Qing,ZOU De-Chun.Synthesis of Liquid Crystal Porphyrin Compounds with Chiral Side Chains and Their Luminescent Characterization[J].Acta Chimica Sinica,2004,62(24):2425-2430. |
| |
| Authors: | LUO Kai-Jun XIE Ming-Gui JIANG Qing ZOU De-Chun |
| |
| Institution: | 1. College of Chemistry, Sichuan University, Chengdu 610016;2. Testing Center, Sichuan Normal University, Chengdu 610066;3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 |
| |
| Abstract: | Two series of liquid crystal tetraporphyrins with chiral side chains were synthesized. Their structures were characterized by elemental analysis, UV-vis, FT-IR, 1H NMR, MS, DSC and CD. The results show that they have the liquid crystal, solid photoluminescent and electroluminescent properties. Among them, two porphyrin compounds have the strong cotton absorption effect. |
| |
| Keywords: | porphyrin liquid crystal synthesis circular dichroism (CD) photoluminescence (PL) electroluminescence (EL) |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
| 点击此处可从《化学学报》下载免费的PDF全文 |
|
