Kinetics of the ionization of monoalkylbenzenes and nitroalkanes in polar solvents. 1. Model of reaction and expression for rate constant |
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| Authors: | N. G. Zharova É. D. German A. M. Kuznetsov I. O. Shapiro |
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| Affiliation: | 1. L. Ya. Karpov Scientific-Research Institute of Physical Chemistry, Moscow
2. A. N. Frumkin Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow
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| Abstract: | | 1. | The influence of the components of the effect of the structural reorganization of the anionic fragments of monalkylbenzenes and nitroalkanes on the kinetics of their ionization was determined. | | 2. | A model of the mechanism of the elementary act in the ionization of monoalkylbenzenes and nitroalkanes in a polar medium, which takes into account the effects of the reorganization of the solvent, the geometric structure of the reactants, and the redistribution of the electron density in them, has been proposed. |
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 318–325, February, 1989. |
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