Fluorocarbon derivatives of nitrogen. Part 10. Preparation of heptafluoro- and 1-chlorohexafluoro-2-nitrosopropane,and conversion on the latter to chloropentafluoroacetone oxime期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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Fluorocarbon derivatives of nitrogen. Part 10. Preparation of heptafluoro- and 1-chlorohexafluoro-2-nitrosopropane,and conversion on the latter to chloropentafluoroacetone oxime

Authors:	Ronald E Banks Neil Dickinson Alan P Morrissey Adrian Richards

Institution:	Chemistry Department, The University of Manchester Institute of Science and Technology, Manchester, M60 1QD UK

Abstract:	Details are given for the preparation of heptafluoro-2-nitrosopropane and 1-chlorohexafluoro-2-nitrosopropane $via$ the routes CF₃CFCF₂ → with CsFR_FCO₂Ag (R_F = CF₃, nC₃F₇)] (CF₃)₂CFAg → (with NOCl) (CF₃)₂CFNO and CF₃CFCF₂ → (with CsClNOCl) CF₃(CF₂Cl)CFNO, respectively, and for conversion of the latter nitroso-compound to chloropentafluoroacetone oxime $via$ reduction with aqueous potassium hydrogen sulphite.

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