Synthesis and unprecedented oxidation of a cationic Sb-analogue of an Arduengo's carbene |
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| Authors: | Gudat Dietrich Gans-Eichler Timo Nieger Martin |
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| Affiliation: | Institut für Anorganische Chemie, Universit?t Stuttgart, 70550, Stuttgart, Germany. gudat@iac.uni-stuttgart.de |
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| Abstract: | ![]()
2-chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb-Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene-SbCl3 complex. |
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