First example of a tetra-carboxylate bridged dimanganese species |
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| Authors: | Grirrane Abdessamad Pastor Antonio Galindo Agustín Ienco Andrea Mealli Carlo Rosa Patrick |
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| Affiliation: | Departamento de Química Inorgánica, Universidad de Sevilla, Aptdo 553, 41071 Sevilla, Spain. |
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| Abstract: | ![]()
The compound [Mn(tda)(bipy)] (tda = S(CH2COO)2(2-)) features the first structurally characterized tetra-carboxylate dimanganese antiferromagnetic system with 'copper acetate' core; the binuclear units, completed by bipyridine chelates, are doubly chained by the tda anions that adopt an unprecedented mu,mu'-eta1,eta1,eta1,eta1 coordination mode. |
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