Aqueous organometallic reactions of rhodium porphyrins: equilibrium thermodynamics |
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| Authors: | Fu Xuefeng Basickes Leah Wayland Bradford B |
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| Institution: | Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA. |
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| Abstract: | The reactivity and equilibrium thermodynamic studies of tetra-p-sulfonatophenyl porphyrin rhodium hydride ((TSPP)Rh-D]-4) with CO, aldehydes and olefins that produce formyl, alpha-hydroxyalkyl and alkyl complexes have been explored in water and compared with the related reactions in non-aqueous media. |
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