A comparative study of the reactions of fluorinated oxi- and thiiranes with acyl chlorides |
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Authors: | S. A. Nalet´ko M. G. Pervova M. I. Kodess M. S. Toporova T. I. Gorbunova A. Ya. Zapevalov V. I. Saloutin |
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Affiliation: | 1.I. Ya. Postovsky Institute of Organic Synthesis,Ural Branch of the Russian Academy of Sciences,Ekaterinburg,Russian Federation |
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Abstract: | The CoCl2-catalyzed reactions of fluorinated 1,2-oxi- and thiiranes with acyl chlorides were studied. It was found that a regioselective heterocycle opening reaction resulted in two isomers having normal and abnormal structure in a ratio predetermined by the substituents in both the starting heterocycles and acyl chlorides. |
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