| Synthesis and Crystal Structure of Cd（tla）（NO_3）_2［TLA＝tris（6－methyl－2－pyridylmethyl） amine］ |
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| 引用本文： | BU Xian-He, ZHANG Zhi-Hui, ZHU Zhi-Ang, CHEN Yun-Ti(Department of Chemistry,Nankai University,Tianjin 300071). Synthesis and Crystal Structure of Cd（tla）（NO_3）_2［TLA＝tris（6－methyl－2－pyridylmethyl） amine］[J]. 结构化学, 1996, 0(5) |
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| 作者姓名： | BU Xian-He ZHANG Zhi-Hui ZHU Zhi-Ang CHEN Yun-Ti(Department of Chemistry Nankai University Tianjin 300071) |
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| 作者单位： | Department of Chemistry，Nankai University，Tianjin 300071 |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣｄ（ｔｌａ）（ＮＯ_３）_２［ＴＬＡ＝ｔｒｉｓ（６－ｍｅｔｈｙｌ－２－ｐｙｒｉｄｙｌｍｅｔｈｙｌ）ａｍｉｎｅ］ＢＵＸｉａｎ－Ｈｅ；ＺＨＡＮＧＺｈｉ－Ｈｕｉ；ＺＨＵＺｈｉ－Ａｎｇ；ＣＨＥＮＹｕ...
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| 关 键 词： | cadmium(Ⅱ) complex crystal structure tris(6-methyl-2-Pyridylmethyl) amine |
Synthesis and Crystal Structure of Cd(tla)(NO_3)_2[TLA=tris(6-methyl-2-pyridylmethyl) amine] |
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| BU Xian-He, ZHANG Zhi-Hui, ZHU Zhi-Ang, CHEN Yun-Ti. Synthesis and Crystal Structure of Cd(tla)(NO_3)_2[TLA=tris(6-methyl-2-pyridylmethyl) amine][J]. Chinese Journal of Structural Chemistry, 1996, 0(5) |
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| Authors: | BU Xian-He ZHANG Zhi-Hui ZHU Zhi-Ang CHEN Yun-Ti |
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| Abstract: | The title complex has been synthesized and its crystal structure was determined by X-ray diffraction. Prisms of Cd (C_(21)H_(24)N_4)(NO_3)_2(1) crystallize in the triclinic space group P with cell dimensions a= 8.112(1),b=8. 837(2), c=17.236(4),α=78. 80(2),β=89. 99(2),γ=74. 35(2)°,V=1167.4(6),Mr=568. 86, Z=2, F(000)=576,μ= 9.78 cm-1 and Dc= 1. 618 g/cm￣3. 2756 unique reflections with I≥3σ(I) on refinement afforded values of R=0. 047 and R_w=0. 055.The Cd(Ⅱ) atom is surrounded by three oxygen atoms from two nitrate groups and three nitrogen atoms from TLA ligand in a distorted octahedron. |
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| Keywords: | cadmium(Ⅱ) complex crystal structure tris(6-methyl-2-Pyridylmethyl) amine |
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