Ion-exchange resins in non-aqueous solvents-I Sorption rates of p-nitroaniline and the effects of small amounts of water

The rates of sorption of p-nitroaniline onto three hydrogenform resins in methanol, ethanol, n-propanol, isopropanol, n-butanol, acetonitrile, benzene, acetic acid and dioxan are reported. Two of the resins are typical gel-type, microreticular, sulphonated resins and the third is a new, highly porous and rigid, macroreticular, sulphonated resin, Amberlyst 15. There appears to be a correlation between viscosity or dielectric constant and the time for maximum sorption or maximum distribution coefficient when the alcohols are used, but no correlation for all the solvents is apparent. The macroreticular resin still functions when dry, even in the presence of non-polar solvents, but the microreticular resin does not. Small amounts of water present in the solvent or resin aid the sorption of the amine onto both types of resin. The effect of mesh size and cross-linkage are examined.