Arylmagnesiation of alkynes catalyzed cooperatively by iron and copper complexes |
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| Authors: | Shirakawa Eiji Yamagami Takafumi Kimura Takahiro Yamaguchi Shigeru Hayashi Tamio |
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| Affiliation: | Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. shirakawa@kuchem.kyoto-u.ac.jp |
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| Abstract: | ![]()
Iron and copper complexes cooperatively catalyzed the arylmagnesiation of unfunctionalized alkynes including dialkylacetylenes, where the presence of both iron and copper catalysts is essential for high yields of 2-aryl-1-alkenylmagnesium bromides. |
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