| 辐射接枝共聚合反应及其在有机生物医用材料制备中的应用 |
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| 引用本文： | 张涛,侯小东,曹阿民.辐射接枝共聚合反应及其在有机生物医用材料制备中的应用[J].有机化学,2006,26(9):1328-1334. |
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| 作者姓名： | 张涛 侯小东 曹阿民 |
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| 作者单位： | 1. 上海交通大学化学化工学院,上海,200240;中国科学院上海有机化学研究所,上海,200032
2. 中国科学院上海有机化学研究所,上海,200032 |
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| 基金项目： | 上海市科委纳米中心专项(No.0452nm050)资助项目. |
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| 摘 要： | γ-射线辐射高分子材料表面接枝共聚合是一种绿色的、重要的有机生物材料合成制备方法. 综述了γ-射线辐射接枝共聚反应的原理、特点, 阐述了预辐射接枝共聚和共辐射接枝共聚的方法, 介绍了当前γ-射线辐射接枝共聚反应在改善有机生物医用材料的表面亲水性、生物相容性等方面的应用. 对辐射接枝共聚合制备功能药物载体研究进行了简要介绍.
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| 关 键 词： | γ-射线 辐射接枝共聚 预辐射 共辐射 有机生物医用材料 |
| 收稿时间： | 06 28 2006 12:00AM |
| 修稿时间： | 07 14 2006 12:00AM |
Irradiation Graft Copolymerization and Its Application forPreparation of Organic Biomedical Materials |
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| ZHANG Tao,HOU Xiao-Dong,CAO A-Min.Irradiation Graft Copolymerization and Its Application forPreparation of Organic Biomedical Materials[J].Chinese Journal of Organic Chemistry,2006,26(9):1328-1334. |
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| Authors: | ZHANG Tao HOU Xiao-Dong CAO A-Min |
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| Institution: | a College of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240;b Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032 |
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| Abstract: | Irradiation graft copolymerization becomes a green and important synthetic strategy for surface functionalization and facile preparation of new organic biomedical materials. This article reviews the principles and features of γ-ray irradiation graft copolymerization, and summarizes the biomedical applications of irradiation graft copolymerization to tailor surface from hydrophobicity to hydrophilicity, and their functionalization. Furthermore, as novel synthetic approach, the irradiation copolymerization was also employed to prepare new materials as functional drug carrier with controlled release. |
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| Keywords: | γ-ray irradiation graft copolymerization pre-irradiation mutual radiation organic biomedical materials |
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