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Vanadium(V) complexes in sulfuric acid solutions
Authors:L. D. Kurbatova  D. I. Kurbatov
Affiliation:(1) Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620219, Russia
Abstract:
The ionic state of vanadium(V) is studied spectrophotometrically over a wide range of sulfuric acid concentrations from 1.0 to 16.8 mol/l. Existence regions for monomeric and dimeric vanadium(V) complexes are determined. The equilibrium constant of vanadium(V) dimerization in 12 M H2SO4 is determined.
Keywords:
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