Thermal activation of complexation reaction on aerosil surface |
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Authors: | V P Kondilenko V Ya Chorny and A M Eremenko |
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Institution: | (1) Institute of Surface Chemistry, Ukrainian Academy of Sciences, Kiev, Ukraine |
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Abstract: | The influence of temperature in the 20–100°C range on processes of bimolecular interaction in the aerosil-phenanthrene-trinitrobenzene system has been studied. Temperature-stimulated CTC accumulation on the surface is found. Activation energies of complex formation are estimated. Quenching of phenanthrene fluorescence by acceptor has a mixed static and dynamic character. |
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