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Fluorescent conjugated polymers for chemical and biochemical sensing
Authors:Adrian Alvarez  José M Costa-Fernández  Rosario Pereiro  Alfredo Sanz-Medel  Alfonso Salinas-Castillo
Institution:Department of Physical and Analytical Chemistry, University of Oviedo, Avda. Julian Claveria 8, E-33006 Oviedo, Spain;Department of Analytical Chemistry, Faculty of Sciences, University of Granada, Granada, Spain
Abstract:This review deals with the emerging field of fluorescent conjugated polymers for the development of chemical and/or biochemical sensors. As a result of their amplified physical properties due to a “molecular wire effect”, these materials offer excellent characteristics to develop different sensing schemes (e.g., employing direct superquenching or relying on development of fluorescence-resonance-energy-transfer formats). The versatility of their synthesis procedures allows us to introduce the desired functional groups to achieve analytically useful interactions with analytes e.g., from transition-metal ions to explosives, or even, in recent years, relevant biomolecules (e.g., proteins or DNA, where conformational changes play a decisive role in detection)].
Keywords:Biochemical sensing  Chemical sensing  Conjugated polymer  Conjugated polyelectrolyte  DNA sensing  Explosives sensing  Fluorescence  Fluorescence resonance energy transfer (FRET)  Metal-ion sensing  Molecular wire effect
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