| Hydrothermal Synthesis and Crystal Structure of a Novel Isophthalate-bridged Copper(II) Polymer with Two-dimensional Network Structure: [Cu_2(phen)(ipt)_2]_(2n)·nH_2O (ipt = isophthalate, phen = 1,10-phenanthroline) |
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| 引用本文： | CUI Yun-Chenga LI Xiu-Meib① LI Chuan-Bia WANG Qing-Weia LIU Boa LI Guo-Fenga a.Hydrothermal Synthesis and Crystal Structure of a Novel Isophthalate-bridged Copper(II) Polymer with Two-dimensional Network Structure: [Cu_2(phen)(ipt)_2]_(2n)·nH_2O (ipt = isophthalate, phen = 1,10-phenanthroline)[J].结构化学,2005(12). |
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| 作者姓名： | CUI Yun-Chenga LI Xiu-Meib① LI Chuan-Bia WANG Qing-Weia LIU Boa LI Guo-Fenga a |
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| 作者单位： | CUI Yun-Chenga LI Xiu-Meib① LI Chuan-Bia WANG Qing-Weia LIU Boa LI Guo-Fenga a (Jilin Normal University，Siping，Jilin 136000，China) b(Department of Chemistry，Tonghua Teachers college，Tonghua，Jilin 134002，China) |
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| 摘 要： | 1 INTRODUCTION donor due to the presence of the protonated carboxyl group; (d) it can form short bridges via one car- Coordination polymers are of great interest due to boxylato end or long bridges via the benzene ring7]. their physical properties and potential applications in We believe that coordination functionality of isoph- functional materials1~3]. Aromatic polycarboxylic acids thalate can lead to interesting structures. In this com- such as 1,2,4,5-benzenetetracarboxylic acid4],…
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Hydrothermal Synthesis and Crystal Structure of a Novel Isophthalate-bridged Copper(II) Polymer with Two-dimensional Network Structure: [Cu_2(phen)(ipt)_2]_(2n)·nH_2O (ipt = isophthalate,phen = 1,10-phenanthroline) |
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| Abstract: | A novel metal-organic coordination polymer Cu2(phen)(ipt)2]2n?nH2O 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P21/c with a = 12.338(3), b = 12.167(3), c = 18.167(4) ?, β = 111.686(14)o, V = 2534.1(10) ?3, C28H18Cu2N2O9, Mr = 653.52, Dc = 1.713 g/cm3, μ(MoKα) = 1.740 mm?1, F(000) = 1320, Z = 4, the final R = 0.0443 and wR = 0.0853 for 3543 observed reflections (I > 2σ(I)). It exhibits a novel two-dimensional network with tetra- Cu-ipt- as building units. |
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| Keywords: | isophthalate coordination polymer hydrothermal synthesis crystal structure |
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