Chains of fused rings in the hydrogen‐bonded structure of meso‐6,13‐diamino‐6,13‐dimethyl‐1,4,8,11‐tetraazacyclotetradecane–2,2′‐biphenol (1/2) |
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Authors: | Alan J Lough Richard M Gregson George Ferguson Christopher Glidewell |
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Abstract: | The title compound is a salt, C12H32N6]2+·2HOC6H4C6H4O]?. The centrosymmetric cation contains two intramolecular N—H?N hydrogen bonds with an N?N distance of 2.8290 (13) Å, and the pendent amino groups are in axial sites; the anion contains an intramolecular O—H?O hydrogen bond with an O?O distance of 2.4656 (11) Å. The ions are linked into continuous chains by means of four types of N—H?O hydrogen bonds with N?O distances ranging from 2.7238 (12) Å to 3.3091 (13) Å, associated with N—H?O angles in the range 148–160°. |
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