Abstract: | In the crystal structure of the title compound, 3,4,5‐trihydroxybenzoic acid monohydrate, C7H6O5·H2O, the gallic acid molecule has an intramolecular hydrogen bond involving a pair of hydroxyl groups, and it is also linked to a water molecule by a three‐centre (bifurcated) OW—H?O hydrogen bond. The packing of the molecules is stabilized by intermolecular O—H?O and C—H?O hydrogen bonds. |