trans‐Bis(diethanolamine)bis(isothiocyanato)nickel(II) |
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Authors: | Veysel T Yilmaz Ahmet Karadag Carsten Thne Regine Herbst‐Irmer |
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Institution: | Veysel T. Yilmaz,Ahmet Karadag,Carsten Thöne,Regine Herbst‐Irmer |
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Abstract: | In the neutral title complex, trans‐bis(2,2′‐iminodiethanol‐N,O)bis(isothiocyanato)nickel(II), Ni(NCS)2(C4H11NO2)2], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The molecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice. |
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