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trans‐Bis­(diethano­lamine)­bis­(iso­thio­cyanato)­nickel(II)
Authors:Veysel T Yilmaz  Ahmet Karadag  Carsten Thne  Regine Herbst‐Irmer
Institution:Veysel T. Yilmaz,Ahmet Karadag,Carsten Thöne,Regine Herbst‐Irmer
Abstract:In the neutral title complex, trans‐bis(2,2′‐imino­di­ethanol‐N,O)­bis­(iso­thio­cyanato)­nickel(II), Ni(NCS)2(C4H11NO2)2], the iso­thio­cyanate ions and the di­ethanol­amine mol­ecules act as mono­dentate and bi­dentate ligands, respectively. The NiII ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS—Ni—Namine and NNCS—Ni—Oamine bond angles of 88.78 (10) and 89.44 (10)°, respectively. The Ni—N bond distances are in the range 2.069 (3)–2.096 (2) Å. The mol­ecules are linked by hydrogen bonds to form a three‐dimensional infinite lattice.
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