Abstract: | The title compound, di‐μ‐diethylamido‐N:N‐bischlorodimethyltin(IV)], consists of discrete Sn2Cl2(CH3)4(C4H10N)2] dimer molecules, with Sn atoms linked by bridging diethylamido groups. The coordination geometry about the metal atom is distorted trigonal bipyramidal, with the two methyl C atoms and one N atom in the equatorial plane, and the Cl and second N atom in axial positions. |