Dimethylphenylsulfonium trifluoromethanesulfonate and methyldiphenylsulfonium trifluoromethanesulfonate |
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Authors: | Kerstin Schulze‐Matthi Jürgen Bendig Petra Neubauer Burkhard Ziemer |
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Institution: | Kerstin Schulze‐Matthäi,Jürgen Bendig,Petra Neubauer,Burkhard Ziemer |
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Abstract: | The bonding geometry of sulfur in the cations of the title compounds, C8H11S+·CF3SO3? and C13H13S+·CF3SO3?, respectively, is similar and is independent of the ratio of the Me/Ph substituents. As expected, in both cations, the S—Ph bonds are somewhat shorter than the S—Me bonds. In both crystal structures, the interaction between cations and anions is similar. |
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