2,2‐Dimethyl‐1‐(2,4,6‐trinitrophenyl)hydrazine |
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Authors: | J Wilson Quail John A Weil Malvinder P Singh |
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Abstract: | The title molecule (DMPH‐H), C8H9N5O6, was investigated to provide comparison with 2,2‐diphenyl‐1‐picrylhydrazine, which unlike DMPH‐H is readily oxidizable to form a well known stable free radical (DPPH). The structure shows essential differences in the configuration of the hydrazine‐N atoms, the ortho‐nitro group orientations and the crystal packing. The bond angles of the dimethylamino N atom 107.90 (13), 108.96 (12) and 112.21 (13)°] are consistent with a tetrahedral N atom and sp3 hybridization. |
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