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(μ‐C‐meso‐5,5,7,12,12,14‐Hexa­methyl‐1,4,8,11‐tetra­aza­cyclo­tetra­decane‐N‐acetato‐1κ5N,N′,N′′,N′′′,O:2κO′)­tetra­chloro‐1κCl,2κ3Cl‐cobalt(III)­zinc(II)
Authors:Kaliyamoorthy Panneerselvam  Tian‐Huey Lu  Ta‐Yung Chi  Shu‐Fang Tung  Chung‐Sun Chung
Abstract:The crystal structure of the title compound, CoCl(C18H37N4O2){ZnCl3}], has been determined by X‐ray diffraction.Cmeso‐5,5,7,12,12,14‐Hexa­methyl‐1,4,8,11‐tetra­aza­cyclotetradecane‐N‐acetate acts as a bridging ligand to coodinate with CoIII and ZnII ions. The CoIII ion is six‐coordinate in a nearly octahedral environment provided by one Cl atom, four N atoms of the bridging ligand, and one O atom. The ZnII ion is four‐coordinate in a distorted tetrahedral environment completed by three Cl atoms and an O atom of the bridging ligand.
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