Abstract: | The low‐temperature crystal structure of bis(ethylenedithio)tetrathiafulvalene (BEDT‐TTF), C10H8S8, is similar to its high‐temperature structure. The room‐temperature central bond lengths of this molecule are often used as reference in empirical methods to estimate the charge carried by the (BEDT‐TTF)xn+ cations in the BEDT‐TTF molecule‐based organic conductors. We show that the method we previously reported can still be used with low‐temperature BEDT‐TTF salts data. Moreover, we confirm the purely thermal origin of the ordering of the ethylene group. |