Abstract: | All three independent molecules in the triclinic modification of (O‐isopropyl dithiocarbonato‐S)triphenyltin, [Sn(C6H5)3(C4H7OS2)], show tetrahedral coordination at their Sn atoms. Bond dimensions involving the Sn atoms are similar to those found in the monoclinic modification of the same compound. Two of the independent molecules are related by a pseudo‐translation allowing a stacking fault that reduces the intensities of h + k odd reflections. |