Abstract: | The Sn atom in the crystal structure of the title compound,catena‐polytrimethyltin‐μ‐(2,5‐dioxo‐2,5‐dihydropyrrol‐1‐yl)acetato‐O:O′]], Sn(CH3)3(C6H4NO4)], adopts a distorted trigonal bipyramidal coordination geometry with three methyl groups defining the trigonal plane mean Sn—C 2.117 (11) Å] and the axial positions occupied by O atoms from different carboxylate groups, with significantly different Sn—O bond lengths 2.207 (5) and 2.358 (6) Å]. The structure forms a polymeric chain of complex molecules linked via carboxylate moieties. |