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The Preparation of Surface Chemically Pure Sodiumn-Dodecyl Sulfate by Foam Fractionation
Authors:John David Hines
Affiliation:Unilever Research Port Sunlight Laboratory, Quarry Road East, Bebington, Wirral, L63 3JW, England
Abstract:
A novel procedure for the purification to surface chemical standard of sodiumn-dodecyl sulfate and its retrieval as a solid is presented. As a result of their nature and relative surface activity with respect to the product, very small amounts of impurity can significantly alter the result of surface tension experiments. In addition to the preparation, the surface chemical behavior of the product is analyzed and compared with previously published data. Additional suggested criteria for purity are also applied, and their validity is discussed.
Keywords:surfactant   interface   dodecanol   anionic   alcohol   contaminant   critical micelle concentration (CMC)   Gibbs surface concentration   area per molecule   adsorption
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