A hydrogenation product derived from the diterpenoid barbatusin:A revised structure |
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Authors: | Raymond Zelnik Hugo E. Gottlieb David Lavie |
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Affiliation: | 1. Department of Organic Chemistry, Instituto Butantan, São Paulo, Brasil;2. Department of Organic Chemistry, The Weizmann Institute of Science, Rehovot, Israel |
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Abstract: | The structure of the hydrogenation product of barbatusin, a diterpenoid from Coleus barbatus Bentham has been revised on the basis of NMR and X-ray data. A geminal coupling of unusually high magnitude has been observed and analysed. |
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