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The hydrophobic interaction between macroscopic surfaces
Authors:Hugo K Christenson   Per M Claesson  Richard M Pashley
Affiliation:(1) Department of Applied Mathematics, Research School of Physical Sciences, Australian National University, 2600 Canberra, ACT, Australia;(2) Department of Chemistry, The Faculties, Australian National University, 2600 Canberra, ACT, Australia;(3) Present address: Department of Physical Chemistry, The Royal Institute of Technology, S-100 44 Stockholm, Sweden
Abstract:
The aim of this paper is to review our current level of knowledge of the interaction between hydrophobic surfaces immersed in water. The strong attractive forces observed between such surfaces have generally been referred to as “the hydrophobic interaction”. Although the precise origin of this force has not yet been determined, we will examine recent experimental studies and relate them to other phenomena like cavity formation and repulsive hydration forces.
Keywords:Hydrophobic interaction  hydrophobic force  cavitation  surfactant monolayers  force measurements  hydration force
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