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High Molecular Weight Poly(butyl methacrylate) via ATRP Miniemulsions
Authors:Ryan W. Simms  Michael F. Cunningham
Affiliation:Department of Chemical Engineering, Queen's University, Kingston, Ontario, Canada, K7L 3N6
Abstract:Summary: The reverse atom transfer radical polymerization of butyl methacrylate in miniemulsion, initiated with the redox pair hydrogen peroxide/ascorbic acid and mediated with copper(II) bromide tris[2-di(2-ethylhexyl acrylate)aminoethyl]amine is capable of producing well-controlled high-molecular weight poly(butyl methacrylate).
Keywords:atom transfer radical polymerization (ATRP)  high molecular weight  miniemulsion
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