| Structural Effect on Eu(fod)_3-Catalyzed Rearrangement of Allylic Esters |
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| 作者姓名： | 戴伟民 麦咏良 |
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| 作者单位： | Department of Chemistry，Zhejiang University，Hangzhou，Zhejiang 310027，ChinaDepartment of Chemistry，The Hong Kong University of Science and Technology，Clear Water Bay，Kowloon，Hong Kong SAR，China，Department of Chemistry，The Hong Kong University of Science and Technology，Clear Water Bay，Kowloon，Hong Kong SAR，China |
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| 基金项目： | Project supported by the Department of Chemistry,The Hong Kong University of Science and Technology. |
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| 摘 要： | A detail study on the Eu(fod)_3-catalyzed rearrangement of al-lylic esters was described. A significant effect of the substituentsat the allylic backbone was observed. The migrating tendencyof the alkoxyacetates was established in the order of p-CF_3C_6H_4CH_2OCH_2CO_2>MeOCH_2CO_2>PhCH_2OCH_2CO_2>p-MeOC_6H_4CH_2OCH_2CO_2.
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Structural Effect on Eu(fod)_3-Catalyzed Rearrangement of Allylic Esters |
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| DAI,Wei-Min MAK,Wing-Leung.Structural Effect on Eu(fod)_3-Catalyzed Rearrangement of Allylic Esters[J].Chinese Journal of Chemistry,2003(7). |
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| Authors: | DAI Wei-Min MAK Wing-Leung |
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| Institution: | DAI,Wei-Min MAK,Wing-Leung
Department of Chemistry,Zhejiang University,Hangzhou,Zhejiang 310027,China
Department of Chemistry,The Hong Kong University of Science and Technology,Clear Water Bay,Kowloon,Hong Kong SAR,China |
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| Abstract: | A detail study on the Eu(fod)3-catalyzed rearrangement of al-lylic esters was described. A significant effect of the substituents at the allylic backbone was observed. The migrating tendency of the alkoxyacetates was established in the order of p-CF3C6H4CH2OCH2CO2 > MeOCH2CO2 > PhCH2OCH2CO2 > p-MeOC6H4CH2OCH2CO2. |
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| Keywords: | lanthanide allylic ester rearrangement |
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