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Novel simple fluorescent sensor for nickel ions
Authors:Zhe Han  Jing Yan  Hou Quan Tang  Yuan He  Ying Zhu  Yan Qing Ge
Affiliation:1. Environmental Engineering Materials, Advanced Materials Institute, Shandong Academy of Sciences, Jinan, Shandong 250014, PR China;2. School of Chemical Engineering, Taishan Medical University, Taian, Shandong 271016, PR China
Abstract:
A novel pyrazoline with benzimidazole substituent was conveniently synthesized, starting from a chalcone and 2-hydrazinylpyridine. The addition of Ni2+ to ethanol solution of the synthesized pyrazoline resulted in a rapid color change from blue to green which allows the selective detection of Ni2+ ion over a great number of other metal ions. The association constant for the 1:1 complex was determined to be 2.72 × 107 M?1.
Keywords:Pyrazoline  Benzimidazole  Fluorescent sensor  Nickel ion detection
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