Enhanced chromatographic NMR with polyethyleneglycol. A novel resolving agent for diffusion ordered spectroscopy |
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| Authors: | Jari S. Kavakka Viktor Parviainen Kristiina Wähälä Ilkka Kilpeläinen Sami Heikkinen |
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| Affiliation: | Laboratory of Organic Chemistry, Department of Chemistry, University of Helsinki, A.I Virtasen aukio 1, P.O. Box 55, FIN‐00014, Finland |
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| Abstract: | ![]()
NMR analysis of complex mixtures can be significantly simplified using polyethyleneglycol (PEG) as resolving additive in DOSY NMR technique, which allows the extraction of individual spectra of mixture components with differing polarity. Resolving power of PEG‐assisted DOSY was demonstrated with natural product mixtures. Copyright © 2010 John Wiley & Sons, Ltd. |
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| Keywords: | NMR 1H DOSY chromatography PEG mixture analysis |
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