Reaction of 2-substituted 4,4-dimethyl-5-methylene-1,3-dioxolanes with dichlorocarbene and certain transformations of adducts obtained |
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Authors: | P. I. Kazaryan S. V. Avakyan A. A. Gevorkyan R. G. Kulinkovich G. A. Panosyan |
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Affiliation: | 1. Institute of Organic Chemistry, Academy of Sciences of the Armenian SSR, 357094, Erevan
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Abstract: | A series of derivatives of 4,4-dimethyl-5-methylene-1,3-dioxolane has been synthesized, and their reaction with dichlorocarbene, obtained under interphase catalysis conditions, has been studied. The adducts obtained undergo thermal isomerization into dichloroethylidene derivatives. |
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