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Selective Oxidation of Alcohols with a New Reagent: Iron(III) Nitrate Supported on Aluminum Silicate
Authors:Ji‐Dong Lou  Li‐Hong Huang  Aizen J Marrogi  Feng Li  Li Li
Institution:1. College of Life Sciences, China Institute of Metrology , Hangzhou, Zhejiang, China;2. Department of Pathology and Area Laboratory Medicine , Walter Reed Army Medical Center , Washington, DC, USA;3. School of Chemistry, University of Sydney , NSW, Australia
Abstract:A selective and effective oxidation of alcohols, except aliphatic alcohols, such as 1‐hexanol or 1‐octyl alcohol, to the corresponding aldehydes and ketones using a new reagent, iron(III) nitrate supported on aluminum silicate, under heterogeneous conditions with reflux with 85–98% yield is described.
Keywords:alcohol  aluminum silicate  iron (III)  nitrate nonahydrate  oxidation
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