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Homo-Coupling of Terminal Alkynes Using a Simple,Cheap Ni(dppe)Cl2/Ag2O Catalyst System
Authors:Qiang Chen  Li-Peng Zhang
Institution:1. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China;2. University of Chinese Academy of Sciences, Beijing, China
Abstract:A simple Ni(dppe)Cl2/Ag2O combination has been established as an efficient catalyst system for the homo-coupling of aromatic terminal alkynes. This reaction proceeds under mild conditions and can be applied to alkynone substrates. Various aromatic 1,3-diynes were obtained in good to excellent yields.
Keywords:1  3-Diynes  homo-coupling  nickel  terminal alkynes
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