Homo-Coupling of Terminal Alkynes Using a Simple,Cheap Ni(dppe)Cl2/Ag2O Catalyst System |
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Authors: | Qiang Chen Li-Peng Zhang |
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Institution: | 1. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Green Printing, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China;2. University of Chinese Academy of Sciences, Beijing, China |
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Abstract: | A simple Ni(dppe)Cl2/Ag2O combination has been established as an efficient catalyst system for the homo-coupling of aromatic terminal alkynes. This reaction proceeds under mild conditions and can be applied to alkynone substrates. Various aromatic 1,3-diynes were obtained in good to excellent yields. |
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Keywords: | 1 3-Diynes homo-coupling nickel terminal alkynes |
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