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Synthesis of a Novel Dispiroheterocyclic Framework via the Regioselective 1,3‐Dipolar Cycloaddition Reaction of Azomethine Ylides
Authors:A R Suresh Babu
Institution:Department of Organic Chemistry , University of Madras , Chennai, India
Abstract:2‐Arylidene‐1,3‐indanediones undergo regioselective 1,3‐dipolar cycloaddition with the azomethine ylide generated from acenaphthenequinone and sarcosine to afford a rare class of complex dispiropyrrolidines in good yield. Single‐crystal X‐ray crystal analysis of one of the products confirms the structure and regiochemistry of the cycloaddition.
Keywords:azomethine ylide  1  3‐dipolar cycloaddition  spiropyrrolidines
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